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Chemistry

Give balanced equations for the following conversions:

  1. 1,2 dibromoethaneAAcetyleneBSilver acetylide\text{1,2 dibromoethane} \xrightarrow{\text{A}} \text{Acetylene} \xrightarrow{\text{B}} \text{Silver acetylide}
  2. EthanolCEtheneDEthyl iodide\text{Ethanol} \xrightarrow{\text{C}} \text{Ethene} \xleftarrow{\text{D}} \text{Ethyl iodide}
  3. BromoethaneEEthaneFSodium propanoate\text{Bromoethane} \xrightarrow{\text{E}} \text{Ethane} \xleftarrow{\text{F}} \text{Sodium propanoate}
  4. Sodium ethanoateGMarsh gasG1MethanolG2MethanalG3Methanoic acid\text{Sodium ethanoate} \xrightarrow{\text{G}} \text{Marsh gas} \xrightarrow{\text{G}1} \text{Methanol} \xrightarrow{\text{G}2} \text{Methanal} \xrightarrow{\text{G}_3} \text{Methanoic acid}
  5. Sodium acetate + H2HAcetic acidH1Ethyl ethanoate\text{Sodium acetate + H}2 \xleftarrow{\text{H}} \text{Acetic acid} \xrightarrow{\text{H}1} \text{Ethyl ethanoate}

Organic Chemistry

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Answer

1. 1,2 dibromoethaneAAcetylene\text{1,2 dibromoethane} \xrightarrow{\text{A}} \text{Acetylene}

Write balanced chemical equation for the preparation of Ethyne from 1, 2 – dibromoethane and alcoholic potassium hydroxide. Organic Chemistry, Simplified Chemistry Dalal Solutions ICSE Class 10

AcetyleneBSilver acetylide\text{Acetylene} \xrightarrow{\text{B}} \text{Silver acetylide}

HC ≡ CH ethyne+2AgNO3+2NH4OHAg-C ≡ C-AgSilver Acetylide+2NH4NO3+2H2O\underset{\text{ ethyne}}{\text{HC ≡ CH}} + 2\text{AgNO}3 + 2\text{NH}4\text{OH} \longrightarrow \underset{\text{Silver Acetylide}}{\text{Ag-C ≡ C-Ag}} + 2\text{NH}4\text{NO}3 + 2\text{H}_2\text{O}

2. EthanolCEthene\text{Ethanol} \xrightarrow{\text{C}} \text{Ethene}

C2H5OH ethyl alcohol170°CConc. H2SO4[excess]C2H4ethene+H2O\underset{\text{ ethyl alcohol}}{\text{C}2\text{H}5\text{OH}} \xrightarrow[170\degree\text{C}]{\text{Conc. H}2\text{SO}4\text{[excess]}} \underset{ \text{ethene}}{\text{C}2\text{H}4} + \text{H}_2\text{O}\

Ethyl iodideDEthene\text{Ethyl iodide} \xrightarrow{\text{D}} \text{Ethene}

C2H5I ethyl iodide+KOH alcoholicboilC2H4 ethene+KI+H2O\underset{\text{ ethyl iodide}}{\text{C}2\text{H}5\text{I}} + \underset{ \text{ alcoholic}}{\text{KOH}} {\xrightarrow{\text{boil}}} \underset{ \text{ ethene}}{\text{C}2\text{H}4} + \text{KI} +\text{H}_2\text{O}

3. BromoethaneEEthane\text{Bromoethane} \xrightarrow{\text{E}} \text{Ethane}

C2H5Brbromoethane+2[H]nascent hydrogenalcoholZn/Cu coupleC2H6ethane+HBr\underset{\text{bromoethane}}{\text{C}2\text{H}5\text{Br}} + \underset{\text{nascent hydrogen}}{2\text{[H]}} \xrightarrow[\text{alcohol}]{\text{Zn/Cu couple}} \underset{\text{ethane}}{\text{C}2\text{H}6} +\text{HBr}

EthaneFSodium propanoate\text{Ethane} \xleftarrow{\text{F}} \text{Sodium propanoate}

C2H5COONasodium propanoate+NaOHsodalime300°CCaOC2H6ethane+Na2CO3\underset{\text{sodium propanoate}}{\text{C}2\text{H}5\text{COONa}} + \underset{\text{sodalime}}{\text{NaOH}} \xrightarrow[300\degree\text{C}]{\text{CaO}} \underset{\text{ethane}}{\text{C}2\text{H}6 \uparrow} + \text{Na}2\text{CO}3

4. Sodium ethanoateGMarsh gas\text{Sodium ethanoate} \xrightarrow{\text{G}} \text{Marsh gas}

CH3COONa sodium acetate+NaOHsodalime300°CCaOCH4methane+Na2CO3\underset{\text{ sodium acetate}}{\text{CH}3\text{COONa}} + \underset{\text{sodalime}}{\text{NaOH}} \xrightarrow[300\degree\text{C}]{\text{CaO}} \underset{\text{methane}}{\text{C}\text{H}4 \uparrow} + \text{Na}2\text{CO}3

Methane to Methanol to Methanal to Methanoic acid

CH4 MethaneK2Cr2O7[O]CH3OHmethanolK2Cr2O7[O]HCHOmethanalK2Cr2O7[O]HCOOHmethanoic acid\underset{\text{ Methane} }{\text{CH}4} \xrightarrow[\text{K}2\text{Cr}2\text{O}7]{\text{[O]}} \underset{\text{methanol}}{\text{CH}3\text{OH}} \xrightarrow[\text{K}2\text{Cr}2\text{O}7]{\text{[O]}} \underset{\text {methanal}}{\text{HCHO}} \xrightarrow[\text{K}2\text{Cr}2\text{O}_7]{\text{[O]}} \underset{\text{methanoic acid}}{\text{HCOOH}}

5. Sodium acetate + H2HAcetic acid\text{Sodium acetate + H}_2 \xleftarrow{\text{H}} \text{Acetic acid}

2CH3COOHAcetic acid+2Na2CH3COONasodium acetate+H22\underset{\text{Acetic acid}}{\text{CH}3\text{COOH}} + 2\text{Na} \longrightarrow \underset{\text{sodium acetate}}{2\text{CH}3\text{COONa}} + \text{H}_2

Acetic acidH1Ethyl ethanoate\text{Acetic acid}\xrightarrow{\text{H}_1} \text{Ethyl ethanoate}

C2H5OHethyl alcohol+CH3COOHAcetic acidConc. H2SO4CH3COOC2H5ethyl ethanoate+H2O\underset{\text{ethyl alcohol}}{\text{C}2\text{H}5\text{OH}} + \underset{\text{Acetic acid}}{\text{CH}3\text{COOH}} \xrightarrow{\text{Conc. H}2\text{SO}4} \underset{\text{ethyl ethanoate}}{\text{CH}3-\text{COO}-\text{C}2\text{H}5} + \text{H}_2\text{O}

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