Chemistry

Starting from aq. copper (II) sulphate solution, give equations for the reactions at the cathode and anode during electrolysis of aq. CuSO4 using active copper electrodes.

Electrolysis

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Answer

Dissociation of aq. CuSO4 :

CuSO4 ⇌ Cu2+ + SO42-

H2O ⇌ H1+ + OH1-

Electrode reaction:

Reaction at Cathode:
Cu2+ + 2e- ⟶ Cu [Product : Copper metal]

Reaction at anode:
Cu – 2e- ⟶ Cu2+ [Product : Nil , Cu2+ ions ]

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