KnowledgeBoat Logo

Chemistry

(a) State the law which the following graph verifies.

State the law which the graph verifies. Study of Gas Laws, Concise Chemistry Solutions ICSE Class 9.

(b) Derive the mathematical expression for it.

(c) Give one application/use where the above law is employed.

Gas Laws

18 Likes

Answer

(a) Charles' law — It states that pressure remaining constant, the volume of a given mass of dry gas increases or decreases by 1273\dfrac{1}{273} of its volume at 0°C for each 1°C increase or decrease in temperature, respectively.

(b) Let V0 be the volume of a fixed mass of a gas at 0°C and let V be its volume at temperature t°C at constant pressure. Then according to Charles' law,

V = Vo + V0273\dfrac{\text{V}_0}{273}t (when P is constant)

V = Vo (1 + t273\dfrac{\text{t}}{273})

= Vo (273 + t273\dfrac{\text{273 + t}}{273})

V = V0273\dfrac{\text{V}_0}{273}T where T = 273 + t

For a given mass of a gas,

V0273\dfrac{\text{V}_0}{273} = constant

∴ V = k x T (where k is constant)

or V α T and VT\dfrac{\text{V}}{\text{T}} = K

Suppose a gas occupies V1 cm3 at T1 temperature and V2 cm3 at T2 temperature, then by Charles law,

    V1 α T1

or V1 = kT1 (k is constant)

or V1T1\dfrac{\text{V}1}{\text{T}1} = k and

    V2 α T2

or V2T2\dfrac{\text{V}2}{\text{T}2} = k

V1T1\dfrac{\text{V}1}{\text{T}1} = V2T2\dfrac{\text{V}2}{\text{T}2} = k (at constant pressure)

(c) Volume of a given mass of a gas is directly proportional to its temperature, hence, density decreases with an increase in temperature. This is the reason that hot air is filled into balloons used for meteorological purposes.

Answered By

13 Likes


Related Questions