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Chemistry

The percentage composition of sodium phosphate as determined by analysis is 42.1% sodium, 18.9% phosphorus and 39% oxygen. Find the empirical formula of the compound?

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Answer

Element% compositionAt. wt.Relative no. of atomsSimplest ratio
sodium42.12342.123\dfrac{42.1}{23} = 1.831.830.609\dfrac{1.83}{0.609} = 3
phosphorus18.93118.931\dfrac{18.9}{31} = 0.6090.6090.609\dfrac{0.609}{0.609} = 1
oxygen39163916\dfrac{39}{16} = 2.432.430.609\dfrac{2.43}{0.609} = 4

Simplest ratio of whole numbers = Na : P : O = 3 : 1 : 4

Hence, empirical formula is Na3PO4

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