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Chemistry

An organic compound on analysis gave H = 6.48% and O = 51.42%. Determine it's empirical formula if the compound contains 12 atoms of carbon. [C = 12, H = 1, O = 16]

Stoichiometry

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Answer

Element% compositionAt. wt.Relative no. of atomsSimplest ratio
Oxygen51.421651.4216\dfrac{51.42}{16} = 3.2133.2133.213\dfrac{3.213}{3.213} = 1
Hydrogen6.4816.481\dfrac{6.48}{1} = 6.486.483.213\dfrac{6.48}{3.213} = 2.016 = 2
Carbon100 - (51.42 + 6.48) = 42.11242.112\dfrac{42.1}{12} = 3.5083.5083.213\dfrac{3.508}{3.213} = 1.091 = 1

Simplest ratio of whole numbers = O : H : C = 1 : 2 : 1

As number of carbon atoms = 12

Therefore, O : H : C = 12 : 24 : 12

Hence, empirical formula is C12H24O12

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