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A piece of ice of mass 100 g is dropped into 450 g of water at 45°C. Calculate the final temperature of water after all of the ice has melted. (Specific heat capacity of water 4200 Jkg-1°C-1, specific heat of fusion of ice = 336 x 103 Jkg-1)

Calorimetry

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Answer

Given,

mi = 100 g

Converting g to kg

1000 g = 1 kg

So, 100 g = 1001000\dfrac{100}{1000} = 0.1 kg

mw = 450 g

Converting g to kg

1000 g = 1 kg

So, 450 g = 4501000\dfrac{450}{1000} = 0.45 kg

Specific heat capacity of water = 4200 J kg-1 K-1

specific latent heat of fusion of ice = 336 x 103 J kg-1

final temperature of water = ?

Let final temperature = t

Heat energy given out by water when it cools from 45° C to t° C
= m x c x Δt
= 0.45 × 4200 × (45 – t)
= 85050 – 1890t

Heat energy taken by ice when it converts from ice into water at 0° C
= m x L
= 0.1 × 336 x 103 J
= 33600 J

Heat energy taken by water when it raises it's temperature from 0° to t° C
= m x c x Δt
= 0.1 × 4200 × (t – 0)
= 0.1 × 4200 × t
= 420t

If there is no loss of energy,

Heat energy gained = heat energy lost

Substituting the values we get,

33600+420t=850501890t1890t+420t=85050336002310t=51450t=514502310t=22.27°C33600 + 420t = 85050 - 1890t \\[0.5em] 1890t + 420t = 85050 - 33600 \\[0.5em] 2310t = 51450 \\[0.5em] t = \dfrac{51450}{2310} \\[0.5em] t = 22.27° C

Hence, final temperature = 22.27°C

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