Chemistry
State the basic steps with reasons, involved in diluting a beaker of conc. H2SO4.
Sulphuric Acid
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Answer
For dilution of conc. H2SO4, the conc. acid is added to water and not the water to the acid even though heat is evolved in both cases.
- If water is added to the acid : There is a sudden increase in the temperature and the acid being in bulk tends to spurt out.
- If acid is added to water : The water is in bulk and the acid being heavier settles down. The heat evolved is dissipated in the water itself and hence the spurting of the acid is minimized.
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In the Contact process
(i) State how you would convert (a) sulphur (b) iron pyrites to sulphur dioxide in the first step of the Contact process.
(ii) State the conditions i.e. catalyst, promoter, temperature and pressure in the catalytic oxidation of sulphur dioxide to sulphur trioxide in the Contact tower. Give a balanced equation for the same.
(iii) State why the above catalytic oxidation reaction supplies energy.
(iv) Give a reason why – vanadium pentoxide is preferred to platinum during the catalytic oxidation of sulphur dioxide.
(v) Give a reason why the catalyst mass is heated electrically – only initially.
(vi) State why sulphur trioxide vapours are absorbed in concentrated sulphuric acid and not in water to obtain sulphuric acid.
Give a reason why concentrated sulphuric acid is kept in air tight bottles.
Give reasons why dilute sulphuric acid:
(i) behaves as an acid when dilute.
(ii) is dibasic in nature.
Convert dil. H2SO4 to –
(i) Hydrogen
(ii) Carbon dioxide
(iii) Sulphur dioxide
(iv) Hydrogen sulphide
(v) An acid salt
(vi) A normal salt.