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Chemistry

State one appropriate observation for :

(i) Copper sulphide is treated with dilute hydrochloric acid.

(ii) A few drops of dil. HCl are added to AgNO3 soln. followed by addition of NH4OH soln.

Hydrogen Chloride

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Answer

(i) A colourless gas having smell of rotten eggs is given off. The gas evolved is H2S

CuS + 2HCl ⟶ CuCl2 + H2S

(ii) Curdy white precipitate of silver chloride [AgCl] is obtained, which is soluble in excess of NH4OH.

AgNO3 + HCl ⟶ AgCl ↓ + HNO3

AgCl + 2NH4OH ⟶ [Ag(NH3)2Cl)] + 2H2O

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