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Chemistry

Give two tests for dilute sulphuric acid with balanced equations. State why

(i) BaCl2

(ii) Pb(NO3)2

are used for the above tests

Sulphuric Acid

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Answer

(i) BaCl2 solution on treating with dilute sulphuric acid forms white ppt. of barium sulphate, which is insoluble in dilute sulphuric acid.

BaCl2 + H2SO4 (dil) ⟶ 2HCl + BaSO4 ↓ [white ppt. formed]

(ii) Pb(NO3)2 on treating with dilute sulphuric acid gives white ppt of lead sulphate, which is insoluble in dil. H2SO4.

Pb(NO3)2 + H2SO4 (dil) ⟶ 2HNO3 + PbSO4 ↓ [white ppt. formed]

BaCl2 and Pb(NO3)2 are used for the above tests as they react with H2SO4 and form BaSO4 and PbSO4 respectively, which are the only compounds insoluble in dil. sulphuric acid.

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