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Chemistry

Give balanced equations for the following conversions :

(a) Ammonia to nitrogen using an acidic gas.

(b) Ammonia to brown gas.

(c) Ammonia to nitrogen trichloride

(d) Ammonia solution to an amphoteric hydroxide

(e) A nitride of a trivalent metal to ammonia

(f) Lead oxide to lead

Ammonia

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Answer

(a) Ammonia to nitrogen using an acidic gas :

8NH3 [excess] + 3Cl2 ⟶ 6NH4Cl + N2

(b) Ammonia to brown gas:

4NH3+5O2800°CPt.4NO+6H2O+Δ4\text{NH}3 + 5\text{O}2 \xrightarrow[800 \degree \text{C}]{\text{Pt.}} \text{4NO} + \text{6H}_\text{2}\text{O} + \Delta

2NO + O2 ⟶ 2NO2 [brown gas]

(c) Ammonia to nitrogen trichloride

NH3 + 3Cl2 [excess] ⟶ 3HCl + NCl3

(d) Ammonia solution to an amphoteric hydroxide :

AlCl3 + 3NH4OH ⟶ 3NH4Cl + Al(OH)3

(e) A nitride of a trivalent metal to ammonia:

AlN + 3H2O ⟶ Al(OH)3 + NH3

(f) Lead oxide to lead

2NH3 + 3PbO ⟶ 3Pb + 3H2O + N2 [g]

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