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Chemistry

Give a word equation and balanced molecular equation for the laboratory preparation of nitric acid from :

(i) KNO3

(ii) NaNO3.

Nitric Acid

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Answer

(i) Potassium Nitrate [Nitre] + Sulphuric acid [conc.] ⟶ Potassium bisulphate + Nitric acid [vapours]

KNO3[conc.]+H2SO4[conc.]<200°CKHSO4+HNO3\text{KNO}3 [\text{conc.}] + \text{H}2\text{SO}4 [\text{conc.}]\xrightarrow{\lt 200 \degree\text{C}} \text{KHSO}\text{4} + \text{HNO}_\text{3}

(ii) Sodium Nitrate [Chile salt petre]+ Sulphuric acid [conc.] ⟶ Sodium bisulphate + Nitric acid [vapours]

NaNO3[conc.]+H2SO4[conc.]<200°CNaHSO4+HNO3\text{NaNO}3 [\text{conc.}] + \text{H}2\text{SO}4 [\text{conc.}]\xrightarrow{\lt 200 \degree\text{C}} \text{NaHSO}\text{4} + \text{HNO}_\text{3}

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