Chemistry
2. B Electrorefining of copper | Complete and balance the electrode reactions |
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16. Dissociation of aq. copper sulphate | CuSO4 ⇌ …………… + …………… |
H2O ⇌ …………… + …………… | |
17. Reaction at cathode [pure thin sheet of Cu] | Cu2+ + …………… ⟶ …………… [Cu deposited on thin sheet] |
18. Reaction at anode [impure block of active Cu] | Cu - …………… ⟶ …………… [product nil - Cu2+ ions] |
Electrometallurgy of sodium | |
19. Dissociation of sodium chloride fused | NaCl ⇌ …………… + …………… |
20. Reaction at cathode [inert - electrode] | Na1+ + …………… ⟶ …………… [product Na metal] |
21. Reaction at anode [inert - electrode] | Cl1- - …………… ⟶ …………… |
Cl + Cl ⟶ …………… [product Cl2 gas] | |
Electrometallurgy of aluminium | |
22. Dissociation of pure alumina | Al2O3 ⇌ …………… + …………… |
23. Reaction at cathode [inert - electrode] | Al3+ + …………… ⟶ …………… [product Al metal] |
24. Reaction at anode [inert - electrode] | O2- - …………… ⟶ …………… ⟶ 3O2 [product O2 gas] |
Electrolysis
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Answer
2. B Electrorefining of copper | Complete and balance the electrode reactions |
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16. Dissociation of aq. copper sulphate | CuSO4 ⇌ Cu2+ + SO42- |
H2O ⇌ H1+ + OH1- | |
17. Reaction at cathode [pure thin sheet of Cu] | Cu2+ + 2e- ⟶ Cu [Cu deposited on thin sheet] |
18. Reaction at anode [impure block of active Cu] | Cu - 2e- ⟶ Cu2+ [product nil - Cu2+ ions] |
Electrometallurgy of sodium | |
19. Dissociation of sodium chloride fused | NaCl ⇌ Na1+ + Cl1- |
20. Reaction at cathode [inert - electrode] | Na1+ + 1e- ⟶ Na [product Na metal] |
21. Reaction at anode [inert - electrode] | Cl1- - 1e- ⟶ Cl |
Cl + Cl ⟶ Cl2 [product Cl2 gas] | |
Electrometallurgy of aluminium | |
22. Dissociation of pure alumina | Al2O3 ⇌ 2Al3+ + 3O2- |
23. Reaction at cathode [inert - electrode] | 2Al3+ + 6e- ⟶ 2Al [product AL metal] |
24. Reaction at anode [inert - electrode] | 3O2- - 6e- ⟶ 3[O] ⟶ 3O2 [product O2 gas] |
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Related Questions
1. Electrolysis Complete and balance the electrode reactions a. Electrolysis of fused lead bromide 1. Dissociation of lead bromide PbBr2 ⇌ …………… + …………… [ions present Pb2+, Br1-] ] 2. Reaction at cathode [inert-graphite] Pb2+ + …………… ⟶ …………… [product Lead metal] 3. Reaction at anode [inert-graphite] Br1- - …………… ⟶ ……………
Br + Br ⟶ …………… [product Bromine vapours]b. Electrolysis of acidified water 4. Dissociation of acidified water H2SO4 ⇌ …………… + …………… H2O ⇌ …………… + …………… [ions H1+, SO42-, OH1-] 5. Reaction at cathode [inert-platinum] H1+ + …………… ⟶ …………… H + H ⟶ …………… [product Hydrogen gas] 6. Reaction at anode [inert-platinum] OH1- - …………… ⟶ …………… 4OH ⟶ …………… + …………… [product oxygen gas] c. Electrolysis of aq. copper sulphate [Active-copper electrode] 7. Dissociation of aq. copper sulphate CuSO4 ⇌ …………… + …………… [ions present — Cu2+, H1+, SO42-, OH1-]
H2O ⇌ …………… + ……………8. Reaction at cathode [copper (or Pt. or C)] Cu2+ + …………… ⟶ …………… [product copper metal] 9. Reaction at anode [active copper] Cu - …………… ⟶ …………… [product nil - Cu2+ ions] [Inert-platinum electrode]
Dissociation of aq. copper sulphateCuSO4 ⇌ …………… + …………… [ions present — Cu2+, H1+, SO42-, OH1-]
H2O ⇌ …………… + ……………Reaction at cathode [Pt. or Carbon or Cu] Cu2+ + …………… ⟶ …………… [product copper metal] Reaction at anode [inert-Pt. or C] OH1- - …………… ⟶ ……………
4OH ⟶ …………… + …………… [product oxygen gas]2. A : Electroplating Complete and balance the electrode reactions Electroplating of an article with nickle 10. Dissociation of aq. nickle sulphate NiSO4 ⇌ …………… + …………… H2O ⇌ …………… + …………… 11. Reaction at cathode [article to be plated] Ni2+ + …………… ⟶ …………… [Ni deposited on article] 12. Reaction at anode [block of active-nickle] Ni - …………… ⟶ …………… [product nil - Ni2+ ions] Electroplating of an article with silver 13. Dissociation of sodium silver cyanide Na[Ag(CN)2] ⇌ …………… + …………… + …………… H2O ⇌ …………… + …………… 14. Reaction at cathode [article to be plated] Ag1+ + …………… ⟶ …………… [Ag deposited on article] 15. Reaction at anode [block of active-silver] Ag - …………… ⟶ …………… [product nil - Ag1+ ions] During the electrolysis of molten lead bromide, which of the following takes place ?
- Bromine is released at the cathode
- Lead is deposited at the anode
- Bromine ions gain electrons
- Lead is deposited at the cathode
Here is an electrode reaction:
Cu ⟶ Cu2+ + 2e-. [i.e. Cu – 2e- ⟶ Cu2+]
At which electrode (anode or cathode) would such a reaction take place ? Is this an example of oxidation or reduction ?