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2. B Electrorefining of copperComplete and balance the electrode reactions
16. Dissociation of aq. copper sulphateCuSO4 ⇌ …………… + ……………
   H2O ⇌ …………… + ……………
17. Reaction at cathode [pure thin sheet of Cu]Cu2+ + …………… ⟶ …………… [Cu deposited on thin sheet]
18. Reaction at anode [impure block of active Cu]Cu - …………… ⟶ …………… [product nil - Cu2+ ions]
Electrometallurgy of sodium   
19. Dissociation of sodium chloride fusedNaCl ⇌ …………… + ……………
20. Reaction at cathode [inert - electrode]Na1+ + …………… ⟶ …………… [product Na metal]
21. Reaction at anode [inert - electrode]Cl1- - …………… ⟶ ……………
   Cl + Cl ⟶ …………… [product Cl2 gas]
Electrometallurgy of aluminium   
22. Dissociation of pure aluminaAl2O3 ⇌ …………… + ……………
23. Reaction at cathode [inert - electrode]Al3+ + …………… ⟶ …………… [product Al metal]
24. Reaction at anode [inert - electrode]O2- - …………… ⟶ …………… ⟶ 3O2 [product O2 gas]

Electrolysis

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Answer

2. B Electrorefining of copperComplete and balance the electrode reactions
16. Dissociation of aq. copper sulphateCuSO4Cu2+ + SO42-
   H2O ⇌ H1+ + OH1-
17. Reaction at cathode [pure thin sheet of Cu]Cu2+ + 2e-Cu [Cu deposited on thin sheet]
18. Reaction at anode [impure block of active Cu]Cu - 2e-Cu2+ [product nil - Cu2+ ions]
Electrometallurgy of sodium   
19. Dissociation of sodium chloride fusedNaCl ⇌ Na1+ + Cl1-
20. Reaction at cathode [inert - electrode]Na1+ + 1e-Na [product Na metal]
21. Reaction at anode [inert - electrode]Cl1- - 1e-Cl
   Cl + Cl ⟶ Cl2 [product Cl2 gas]
Electrometallurgy of aluminium   
22. Dissociation of pure aluminaAl2O32Al3+ + 3O2-
23. Reaction at cathode [inert - electrode]2Al3+ + 6e-2Al [product AL metal]
24. Reaction at anode [inert - electrode]3O2- - 6e-3[O] ⟶ 3O2 [product O2 gas]

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