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Chemistry

0.2 g atom of silicon combine with 21.3 g of chlorine. Find the empirical formula of the compound formed.

Mole Concept

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Answer

Gram atom = Mass of elementAtomic mass\dfrac{\text{Mass of element}}{\text{Atomic mass}}

g atom of silicon = 0.2 = Mass of silicon28\dfrac{\text{Mass of silicon}}{28}

∴ Mass of silicon = 5.6 g and

Mass of chlorine = 21.3 g

ElementMassAt. wt.gram atomsSimplest ratio
Silicon5.6285.628\dfrac{5.6 }{28} = 0.20.20.2\dfrac{0.2 }{0.2} = 1
Chlorine21.335.521.335.5\dfrac{ 21.3}{35.5} = 0.60.60.2\dfrac{ 0.6 }{0.2} = 3

Simplest ratio of whole numbers = Si : Cl = 1 : 3

Hence, empirical formula is SiCl3

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